By Rose Walano
Updated Aug 06, 2012 @ 5:45 pm
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Credit: Courtesy of Vera Wang

Vera Wang loved Leighton Meester's first Lovestruck ad so much, she asked her to come back for another campaign! Striking another Pretty Woman pose on a fire escape (wearing a bustier dress made especially for the shoot, Wang's representatives tell InStyle.com) the Gossip Girl star embodies Lovestruck Floral Rush's motto of "enchantment and the possibility of love at first sight." The scent boasts decadent notes of champagne accord, apricot blossom, and pink passion flower, and is already available to shop for $78 at macys.com.

See more of summer's sexiest scents.