Emmy Rossum, Cameron Diaz, Kate Bosworth, Jessica Chastain, Diane Kruger
Credit: StartraksPhoto; AP Photo; Getty Images (2); Bauer Griffin

Our favorite outfits of the week—pulled from our Look of the Day top picks—are all about ladylike silhouettes and luxe fabrics. The top five: Emmy Rossum's knee-length tweed Carolina Herrera sheath, Cameron Diaz's retro polka dot Christian Dior design, Kate Bosworth's sexy backless embroidered Antonio Berardi dress, Jessica Chastain's orange and black Armani Prive look, and Diane Kruger's lace peek-a-boo Erdem gown. Which one is your favorite? Vote in the poll below and let us know!MORE:Critics’ Choice Awards: What Everyone WorePeople’s Choice Awards Red Carpet Photos