Kim Kardashian and Kanye West with Amy Schumer
Credit: TIMOTHY A. CLARY/AFP/Getty Images

Leave it to Amy Schumer to bring a dose of humor to last night's Time 100 Gala in New York. The comedian took advantage of Kanye West and Kim Kardashian’s red-carpet arrival to create a memorable moment in photobomb history. In order to pose with the couple, Schumer took a hard-to-miss nose dive into the ground.

In response, Mr. West, who performed later in the evening, gave Schumer his best resting Kanye face while Kardashian gracefully smiled at the prank. Thankfully, Schumer wore a dress comfortable enough for the feat. "This is David Meister and I'm wearing it because I don't have to suck in," she told InStyle. "I've never worn a gown before. I'm psyched!"

Emma Watson
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And while this was by far the night's biggest red carpet occurrence, other stars—including Emma Watson (above), Karlie Kloss, Julianne Moore (below), Laverne Cox, and Bradley Cooper—stepped out to celebrate the honorees. Martha Stewart, who wrote Kim Kardashian's essay for the issue, boasted about the budding entrepreneur: "I think that's one of her great qualities, is that she's a pretty honest, forthright person and what you see is what you get."

Julianane Moore
Credit: Andrew Toth/FilmMagic

Wearing a black Michael Kors vested dress, The Good Wife star and Time 100 honoree Julianna Margulies looked forward to the evening. "I'm really excited ... there's a lot of people I also know, so it's nice to see old friends too, but there isn't one person I don't want to sit and talk to. That's rare," she said.

—With reporting by Cristina Gibson