Taylor Momsen - Thayer
Credit: Courtesy of the CW; Courtesy of ShopBop

It's not everyday that a television series gives fashion a starring role and when a new designer is featured on Gossip Girl, you'd better listen up. Resident rocker Jenny Humphrey (Taylor Momsen) looked quite rebellious on the season premiere last night wearing a snakeskin print maxidress by the next label-to-know, Thayer by Marsha Welcher. While the rest of the girls wore pastel frocks and ladylike hats at the buttoned-up polo match, Little J took the edgy road. Momsen's Thayer maxi is a Barneys exclusive, but we found a similar style in the same cool-girl snakeskin print on

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