Secrets Behind the Hottest Golden Globes Hair and Beauty Looks

Anne Hathaway, 2011

Careful not to clash with her statement dress, Anne Hathaway opted for simple, relaxed waves. To get her look, her hairstylist Adir Abergel first doused wet hair with Fekkai Advanced Full Blown Styling Whip before rough-drying it. "I wanted to let her natural wave surface," he told us. He then pinned still-warm hair in tight curls and allowed it to set. Abergel let Hathaway's hair fall haphazardly when taking the pins out, which determined the part. "I think it gave the style a bohemian vibe," he said.

Taking inspiration from the '60s, hairstylist Renato Campora created a romantic, soft coif for January Jones. He turned to hot rollers to get the Mad Men star's bouncy waves, only lightly brushing through her hair once cooled. Finally, he misted Fekkai Coiff Sheer Hold Hairspray over her 'do for frizz-free strands.

Borrowed from a private Cartier museum in Geneva, Charlize Theron's vintage diamond headband was the basis for hairstylist Enzo Angileri's simple yet chic updo. "Because the jewelry was so special, the hair had to be understated," he told us. To create her look, Angileri pinned and twisted textured hair into an undone bun, spritzing with Moroccanoil Frizz Control to tame flyaways.

"I went for old school Hollywood style with a modern twist," John Frieda celebrity hairstylist Harry Josh said of Rose Byrne's waves. "The shape and silhouette are classic, but I roughed it up and loosened the waves to make the look less uptight." To add polish and sparkle, Josh created a pin-straight part and clipped back her soft, tousled locks with a floral diamond brooch from Neil Lane.

Kate Hudson looked classically chic with dramatically accented eyes and frosted lips. "When I saw Kate in her gorgeous white dress, I knew we had to go for a sophisticated and pretty Grace Kelly-inspired look," her makeup artist Leslie Lopez said. To get Hudson's reversed cat eye, Lopez lined her waterline with a creamy, kohl pencil, extending the thin line just past her tear ducts. For her frosty nude lips, Lopez used Chanel's Aqualumiere Sheer Colour Lipshine in Malta. "It's the perfect sheer and subtle peach," Lopez said of the shade.

Jennifer Lopez showed off her deep chestnut peepers on the red carpet by pulling hair back into a sleek ponytail and accenting her lids with a metallic shadow. Channeling old Hollywood glamour, makeup artist Mary Phillips used a glittering silver shadow, extending powder just past the inner corners of her eyes.

Angelina Jolie's dress wasn't the only thing that sparkled on the red carpet. Known for her seductive lips, Jolie kept her plump pout glossed with Chantecaille's Brilliant Gloss in Love.

Emily Blunt matched her shimmering mauve lids with her floor-length Dolce & Gabbana gown. "Emily wore a pink frilly dress, so we wanted the makeup to be beautiful, soft and feminine," Dior makeup artist Jenn Streicher said of the look. For accented eyes, Streicher blended aubergine and silver shadows, taking the powder just past the star's outer corners and under her eyes. Keeping the rest of her face fairly neutral, Streicher finished the look with a two coats of mascara and a light pink gloss on her lips.

Dianna Agron channeled her inner screen siren with cascading loose waves and rose lips. Hairstylist Danilo wanted to create a classic style that looked sleek but soft. "She was wearing a strapless dress, so she wanted her hair down but off her face," he told us. His solution? Clipping back one side of her hair with a crystal and diamond brooch.

"We wanted to go for something organic, young and modern," hairstylist Mark Townsend said of Lea Michele's beachy updo. After blowing hair dry, Townsend used a 1" curling iron to create piecey ringlets. He then gathered hair and pinned it back into a messy chignon, leaving out layers in the front. He finished the look with a veil of Oribe Dry Texturizing Spray, and scrunched for a lived-in feel.

Hairstylist Campbell McAuley created a romantic, sophisticated updo he called "naturally enchanting" to complement Shailene Woodley's strapless gown. To get the regal look, Campbell suggests using Wella Professionals Velvet Amplified serum before drying hair with a diffuser. "I love this product, it makes hair look healthy and shiny," he said. Once dry, use a 2" curling iron to enhance natural waves. Then, tease the crown and then pull back layers into a loose ponytail before twisting and pinning hair into a low, large bun.

"The look was Hollywood noir," hairstylist Robert Vetica said of Salma Hayek's long, flowing waves. "We added a bit of length to complement the noir vibe." To get the look, Vetica used a round brush while blow drying, to create tons of volume. With a small curling iron, he then curled 2" sections, twisting away from the face. "I kept the curls tight, knowing the length would help it drop into a loose wave," he said. To complete the look, Vetica lightly brushed through the spirals, teased the roots and finally misted with hairspray to keep it intact.

Christina Hendricks added color to her porcelain skin with a tomato lip shade and deep pink cheeks. To fake a natural flush, makeup artist Vanessa Scali used Shu Uemura Satin Radiant Blush Stick for a rosy, translucent shimmer.

Inspired by Emma Stone's sherbet dress, makeup artist Mai Quynh chose similar tones for her face palette. While keeping the rest of Stone's makeup fairly minimal, Quynh focused on the star's peepers, lining the upper lids with a creamy pencil. "I defined her eyes and created golden, dewy skin," Quynh said. For her lips? "It's mark Lipclick Full Color Lipstick in Bare Hug-an absolute must-have nude!"

Zooey Deschanel did not disappoint when it came to turning heads on the red carpet. She stepped out flaunting a new 'do, a back-baring dress and-our favorite-black and white tuxedo manicured nails! "I am wearing a gown but my nails are wearing tuxedos!!!" she tweeted.

Kate Beckinsale showed off her flawless skin with a clean, neutral glow. "By using primer and tinted moisturizer, we were able to admire Kate's natural complexion," makeup artist Molly Stern told us. To highlight the star's cheekbones, Stern used a swirl of bronzer and NARS Highlighting Blush in Miss Liberty to add a hint of peach shimmer to her cheekbones. To accent the actress's eyes, Stern blended gold and brown shadows on her lids, adding a slight wing past her outer corners.