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Grammy Awards 2010

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Gwen Stefani in Vivienne Westwood, 2003

Never pandering for street cred or pretending it's the Oscars, Stefani is always spot-on because she trusts her off-kilter blend of luxe and sleek.

See the night's top moments and best dressed with live Grammys coverage on InStyle.com starting at 6:45 PM EST on Sunday, January 31st.

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