ANGELINA JOLIE & BRAD PITT

Watch Mr. & Mrs. Smith and you'll see that the onscreen chemistry between co-stars Brad Pitt and Angelina Jolie is undeniable. What started as an on-set friendship and one really hot love scene has since turned into a full-blown relationship. The pair embarked on a romantic rendezvous in Africa last May and have since visited each other on location and joined earthquake relief efforts in Pakistan, always with Jolie's adopted children Maddox and Zahara in tow. In early December Pitt began to make his fairy-tale family a reality by filing papers to legally adopt Jolie's kids. Next up, a real-life Mr. & Mrs., perhaps?

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